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Nov 12

Necessary Conditions for Free End-Time Sweeping Process Problems

This paper derives necessary optimality conditions for free end-time optimal control problems governed by sweeping process dynamics. In contrast to classical optimal control problems, the presence of the normal cone term in the state equation introduces discontinuities with respect to the state variable and prevents the standard Lipschitz regularity assumptions typically used in optimal control theory. As a result, both the analysis of trajectories and the formulation of optimality conditions require refined tools. We address problems with general endpoint constraints and time-dependent data, considering both the case in which the dynamics are Lipschitz continuous in time and the more challenging setting of merely measurable time dependence. Special attention is devoted to the additional transversality conditions associated with the free end-time variable. In the Lipschitz case, these conditions are expressed in terms of a function of bounded variation that coincides almost everywhere with the maximized Hamiltonian. In the measurable case, we show that a suitable interpretation can be obtained via the notions of sub- and super-essential values of the maximized Hamiltonian, recently introduced in the literature, leading to strengthened transversality conditions. These conditions also involve an additional term reflecting the interaction between the costate arc and the normal cone to the moving set at the optimal endpoints. Our approach combines suitable perturbation techniques with a penalization method tailored to sweeping processes. The moving set is modelled as a finite intersection of inequality-defined sets satisfying suitable constraint qualifications, including a positive linear independence condition and a diagonal dominance property of the associated Gramian matrix. We also introduce a local version of the constraint qualification condition. Our results apply to a broad class of problems, including those involving unbounded moving sets such as polyhedra. The resulting optimality system extends and sharpens recent results for classical free end-time problems to the non-Lipschitz, discontinuous framework of sweeping processes. The relevance of the transversality conditions obtained in this article is illustrated through two simple examples.

  • 3 authors
·
Oct 6

Extended Detailed Balance for Systems with Irreversible Reactions

The principle of detailed balance states that in equilibrium each elementary process is equilibrated by its reverse process. For many real physico-chemical complex systems (e.g. homogeneous combustion, heterogeneous catalytic oxidation, most enzyme reactions etc), detailed mechanisms include both reversible and irreversible reactions. In this case, the principle of detailed balance cannot be applied directly. We represent irreversible reactions as limits of reversible steps and obtain the principle of detailed balance for complex mechanisms with some irreversible elementary processes. We proved two consequences of the detailed balance for these mechanisms: the structural condition and the algebraic condition that form together the extended form of detailed balance. The algebraic condition is the principle of detailed balance for the reversible part. The structural condition is: the convex hull of the stoichiometric vectors of the irreversible reactions has empty intersection with the linear span of the stoichiometric vectors of the reversible reaction. Physically, this means that the irreversible reactions cannot be included in oriented pathways. The systems with the extended form of detailed balance are also the limits of the reversible systems with detailed balance when some of the equilibrium concentrations (or activities) tend to zero. Surprisingly, the structure of the limit reaction mechanism crucially depends on the relative speeds of this tendency to zero.

  • 2 authors
·
Jan 27, 2011

Constraint closure and gravitational-wave content of shear-free cosmologies in metric f(R) gravity

We derive the consistency conditions governing the propagating content of linear shear-free perturbations of Friedmann-Lema\^ıtre-Robertson-Walker cosmologies in metric f(R) gravity. The divergence of the shear-free constraint is shown to be the total momentum-conservation equation and therefore does not imply geodesic flow. Its projected time derivative instead supplies a nontrivial integrability condition. Scalar, vector, and tensor sectors must then be tested separately. Shear-freeness removes the independent transverse-traceless electric-magnetic Weyl pair, so no ordinary + or times tensor gravitational wave survives. The scalaron is not removed algebraically, but its four-variable harmonic system must remain in the time-dependent consistent subspace generated by the shear-free constraint and all of its time derivatives. For a geodesic shear-free congruence in the spatially flat expanding de Sitter patch, this excludes every nonzero fixed comoving scalar harmonic, including the healthy R+αR^2-2Λ model with α,Λ>0. Vector modes obey a curvature-dependent global eigenvalue condition whose right-hand side is negative for positive-density matter with f'>0 and 1+w>0; hence no nonzero vector harmonic survives on that branch. The familiar coasting R^3 example evades this sign obstruction only because it lies on an f'<0 branch. Thus tensor radiation is absent in the imposed shear-free sector, whereas scalar radiation is not excluded kinematically but remains a model- and background-dependent constraint-closure question.

  • 2 authors
·
Sep 2

Causality and Renormalization in Finite-Time-Path Out-of-Equilibrium φ^3 QFT

Our aim is to contribute to quantum field theory (QFT) formalisms useful for descriptions of short time phenomena, dominant especially in heavy ion collisions. We formulate out-of-equilibrium QFT within the finite-time-path formalism (FTP) and renormalization theory (RT). The potential conflict of FTP and RT is investigated in g phi^3 QFT, by using the retarded/advanced (R/A) basis of Green functions and dimensional renormalization (DR). For example, vertices immediately after (in time) divergent self-energy loops do not conserve energy, as integrals diverge. We "repair" them, while keeping d<4, to obtain energy conservation at those vertices. Already in the S-matrix theory, the renormalized, finite part of Feynman self-energy Sigma_{F}(p_0) does not vanish when |p_0|rightarrowinfty and cannot be split to retarded and advanced parts. In the Glaser--Epstein approach, the causality is repaired in the composite object G_F(p_0)Sigma_{F}(p_0). In the FTP approach, after repairing the vertices, the corresponding composite objects are G_R(p_0)Sigma_{R}(p_0) and Sigma_{A}(p_0)G_A(p_0). In the limit drightarrow 4, one obtains causal QFT. The tadpole contribution splits into diverging and finite parts. The diverging, constant component is eliminated by the renormalization condition langle 0|phi|0rangle =0 of the S-matrix theory. The finite, oscillating energy-nonconserving tadpole contributions vanish in the limit trightarrow infty .

  • 2 authors
·
Dec 31, 2019

CondAmbigQA: A Benchmark and Dataset for Conditional Ambiguous Question Answering

Large language models (LLMs) are prone to hallucinations in question-answering (QA) tasks when faced with ambiguous questions. Users often assume that LLMs share their cognitive alignment, a mutual understanding of context, intent, and implicit details, leading them to omit critical information in the queries. However, LLMs generate responses based on assumptions that can misalign with user intent, which may be perceived as hallucinations if they misalign with the user's intent. Therefore, identifying those implicit assumptions is crucial to resolve ambiguities in QA. Prior work, such as AmbigQA, reduces ambiguity in queries via human-annotated clarifications, which is not feasible in real application. Meanwhile, ASQA compiles AmbigQA's short answers into long-form responses but inherits human biases and fails capture explicit logical distinctions that differentiates the answers. We introduce Conditional Ambiguous Question-Answering (CondAmbigQA), a benchmark with 200 ambiguous queries and condition-aware evaluation metrics. Our study pioneers the concept of ``conditions'' in ambiguous QA tasks, where conditions stand for contextual constraints or assumptions that resolve ambiguities. The retrieval-based annotation strategy uses retrieved Wikipedia fragments to identify possible interpretations for a given query as its conditions and annotate the answers through those conditions. Such a strategy minimizes human bias introduced by different knowledge levels among annotators. By fixing retrieval results, CondAmbigQA evaluates how RAG systems leverage conditions to resolve ambiguities. Experiments show that models considering conditions before answering improve performance by 20%, with an additional 5% gain when conditions are explicitly provided. These results underscore the value of conditional reasoning in QA, offering researchers tools to rigorously evaluate ambiguity resolution.

  • 4 authors
·
Feb 3, 2025